Customization: | Available |
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CAS No.: | 20826-04-4 |
Formula: | C6h4brno2 |
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5-Bromonicotinic acid Chemical Properties |
Melting point | 178-180 °C(lit.) |
Boiling point | 259.67°C (rough estimate) |
density | 1.7477 (rough estimate) |
refractive index | 1.6120 (estimate) |
storage temp. | 2-8°C |
pka | 3.08±0.10(Predicted) |
form | Powder |
color | White to yellow-gray or light brown |
BRN | 115854 |
InChIKey | FQIUCPGDKPXSLL-UHFFFAOYSA-N |
CAS DataBase Reference | 20826-04-4(CAS DataBase Reference) |
Safety Information |
Hazard Codes | Xi |
Risk Statements | 36/37/38 |
Safety Statements | 26-36-24/25 |
WGK Germany | 3 |
RTECS | QT0868000 |
Hazard Note | Irritant |
HazardClass | IRRITANT |
HS Code | 29333999 |
5-Bromonicotinic acid Usage And Synthesis |
Chemical Properties | Light yellow Cryst |
Synthesis Reference(s) | Journal of the American Chemical Society, 70, p. 2381, 1948 DOI: 10.1021/ja01187a020 |
Purification Methods | The acid is recrystallised from H2O and then from EtOH using charcoal. The amide has m 219-219.5o (from aqueous EtOH), and the methyl ester, prepared by addition of ethereal diazomethan e, can be purified by sublimation in a vacuum and has m 98-99o. The acid chloride also can be sublimed in vacuo and has m 74-75o and gives the methyl ester in MeOH. [Graf J Prakt Chem 138 244 1933, Bachman & Micucci J Am Chem Soc 70 2381 1948, Garcia et al. J Am Chem Soc 82 4430 1960, Misic-Vokovic et al. J Chem Soc 34 1978, Beilstein 22/2 V 181.] |